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Showing 271–284 of 284 reference entries

ChemistryInferring empirical and molecular formulas from composition

Element mass ratios become atom ratios through molar masses, with uncertainty and sample identity retained.

Method
ChemistryLewis structures and valence-electron accounting

A Lewis diagram accounts for bonding and nonbonding valence electrons in a specified connectivity.

Method
ChemistryElectron-domain geometry and molecular shape

VSEPR distinguishes the arrangement of electron regions from the positions of atoms.

Model
ChemistryElectronegativity, bond polarity and molecular polarity

Polar bonds can cancel in a molecule; molecular geometry matters.

Model
ChemistrySolutions, solutes, solvents and solvation

Dissolution disperses specified molecular or ionic species in a solvent.

Definition
ChemistrySolubility, saturation and supersaturation

A saturation limit is an equilibrium property under specified conditions, not a synonym for concentration.

Definition
ChemistryFiltration separates retained solids from a fluid

Ordinary filtration separates undissolved particles; dissolved species can remain in the filtrate.

Method
ChemistryDistillation and vapor–liquid composition

Distillation uses vapor–liquid partitioning and condensation, with a limit at an azeotrope.

Method
Biology · ChemistryEnzyme substrates, active sites and induced fit

Substrate recognition and catalysis depend on a dynamic molecular environment.

Model
Biology · ChemistryMonomers, polymers and hydrolysis

Covalent subunit linkage and water-assisted cleavage explain biological polymer structure.

Definition
Biology · ChemistrySugars, glycosidic linkages and polysaccharides

Sugar connectivity distinguishes energy-storage and structural polysaccharides.

Definition
Biology · ChemistryFatty acids, storage lipids and membrane lipids

Lipids include several architectures rather than one repeating-monomer polymer class.

Definition
Biology · ChemistryAmino-acid residues and peptide linkages

The peptide backbone and variable side chains are different parts of protein structure.

Definition
Biology · ChemistryNucleotides and DNA/RNA backbone polarity

Bases carry sequence information on a chemically directional sugar–phosphate backbone.

Definition