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For a cell basis, the kinematic elastic scattering amplitude contains F(G)=Σ_α f_α(G)exp(iG·d_α), and peak intensity is proportional to |F(G)|² with experiment-specific factors.
ModelPhysics · ChemistryHarmonic-chain dispersion and phononsA monatomic chain with mass m, spacing a and nearest-neighbour spring constant κ has ω(k)=2√(κ/m)|sin(ka/2)|.
ModelPhysics · ChemistryAcoustic and optical lattice branchesFor a stable three-dimensional harmonic crystal with s atoms per primitive cell, the displacement dynamical matrix has 3s branches.
ModelPhysics · ChemistryDebye lattice heat capacityThe three-dimensional Debye approximation assigns g(ω)=9Nω²/ω_D³ for 0≤ω≤ω_D so that the mode count is 3N.
ApproximationPhysicsFree-electron Fermi scale and low-temperature heat capacityFor noninteracting spin-½ electrons in a three-dimensional volume, k_F=(3π²n)¹ᐟ³ and E_F=ħ²k_F²/(2m).
ModelPhysics · ChemistryDrude relaxation-time conductivity and Hall responseA single electron-carrier Drude model has dp/dt=−e(E+v×B)−p/τ.
ApproximationPhysicsIndependent-spin paramagnetism and Curie lawFor independent spin-½ moments of magnitude μ in magnetic flux density B, a moment has energies ±μB, partition sum 2cosh(μB/(k_BT)) and mean moment μtanh(μB/(k_BT)).
ModelPhysicsMagnetic order, domains and hysteresisFerromagnetic order aligns moments, antiferromagnetic order has opposing ordered sublattices and ferrimagnetic order has unequal opposing sublattice moments.
ModelPhysicsIdeal-gas Bose condensationFor a uniform three-dimensional ideal gas of spinless bosons in the thermodynamic limit, the excited-state capacity reaches n=ζ(3/2)(mk_BT/(2πħ²))³ᐟ² at T_c.
ModelPhysics · ChemistryGolden-rule weak transition rateA weak coupling from an initial state to a sufficiently dense continuum gives a leading transition rate Γ≈(2π/ħ)|V_fi|²ρ(E_f) at the energy-conserving final energy, for slowly varying matrix elements and density of states.
ApproximationPhysicsTwo-body reduction and reduced massFor two Newtonian particles with equal opposite internal force and no external force, the centre of mass moves uniformly.
ModelPhysics · ChemistryCoupled small-oscillation normal modesNear a stationary equilibrium, a conservative system with quadratic kinetic matrix M and potential Hessian K has Mq̈+Kq=0.
ModelMeasurement · PhysicsAtomic-clock realization of the secondA primary caesium frequency standard relates its oscillator to the defining unperturbed Cs-133 hyperfine transition by estimating and correcting design-dependent shifts, including atomic-motion Doppler and thermal blackbody effects.
MethodMeasurement · PhysicsLength realization by light time and interferometryWith calibrated light frequency f, vacuum wavelength is λ₀=c/f.
MethodMeasurement · PhysicsKibble-balance mass realizationA Kibble balance combines weighing mg=I Bℓ with velocity-mode U=vBℓ to eliminate the common geometry-field factor: mgv=IU.
MethodPhysicsCentral-force effective potential and orbit stabilityFor a conservative central interaction U(r), relative motion is planar and angular momentum L=μr²θ̇ is conserved.
ModelPhysics · Earth & cosmosCoriolis and centrifugal rotating-frame accelerationFor a frame rotating at constant Ω about a common inertial origin, a_inertial=a_rot+2Ω×v_rot+Ω×(Ω×r).
ModelPhysicsHolonomic constraints and multiplier forcesFor ideal independent holonomic constraints f_α(q,t)=0, constrained Lagrange equations can retain redundant coordinates through d(∂L/∂q̇_i)/dt−∂L/∂q_i=Σ_α λ_α∂_i f_α.
MethodPhysicsPoisson brackets and classical conserved observablesIn canonical coordinates, {A,B}=Σ_i[(∂_q_iA)(∂_p_iB)−(∂_p_iA)(∂_q_iB)] and dA/dt={A,H}+∂_tA.
Mathematical statementPhysicsCanonical phase-space transformationsA canonical transformation changes phase-space coordinates and the Hamiltonian while preserving Hamilton's description of the same physical trajectories.
DefinitionPhysicsLensmaker power, magnification and image signsA thin spherical lens in a common surrounding medium has 1/f=(n_lens/n_medium−1)(1/R₁−1/R₂).
ModelPhysicsOptical intensity, coherence and fringe visibilityFor scalar co-polarized fields, averaged intensity includes a cross-correlation term.
ModelPhysicsYoung two-slit fringe geometryFor equal-phase coherent illumination of narrow slits separated by d, far-field bright directions satisfy d sinθ=mλ and dark directions d sinθ=(m+½)λ.
ModelPhysicsScalar paraxial Fresnel propagationA monochromatic scalar field in a uniform medium propagates paraxially as E_z(x,y)≈e^(ikz)/(iλz)∫∫E₀(ξ,η)exp[ik((x−ξ)²+(y−η)²)/(2z)]dξdη, with k=2π/λ.
ModelPhysicsFraunhofer diffraction as an aperture Fourier transformWhen the input-aperture quadratic phase in the Fresnel integral is negligible, the far-field amplitude is proportional to the two-dimensional Fourier transform of the aperture field evaluated at spatial frequencies x/(λz), y/(λz).
ModelPhysicsDiffraction grating orders and spectral dispersionAt normal incidence on a periodic grating of pitch d, principal propagating orders satisfy d sinθ_m=mλ.
ModelPhysicsCircular-aperture diffraction and resolution criterionA uniform ideal circular pupil of diameter D gives an Airy intensity pattern whose first dark ring has small angle θ≈1.22λ/D.
ModelPhysicsCoherent and incoherent image transferFor a linear shift-invariant scalar imaging system, coherent image amplitude is E_image=E_object*h.
ModelPhysicsGroup velocity and pulse-envelope limitsFor a narrow-band wave packet on a smooth real dispersion branch, its leading envelope velocity is v_g=dω/dk at the carrier, while phase velocity is ω/k.
ModelPhysicsFinite well bound-state matchingFor V(x)=−V₀ inside |x|<a/2 and zero outside, bound states have −V₀<E<0.
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