Choose what belongs to an investigation, describe its condition at a stated time, and identify interactions with what lies outside its boundary.
Key knowledge
Describing a system requires identifying its components and interactions, its boundary, and relevant inputs and outputs. What counts as internal or external depends on that chosen boundary.
Conditions and scope
A boundary is part of the model and must be stated before applying a balance law.
Sources · 13
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
NGSS Appendix G, systems and system models; OpenStax 5.3, internal and external forces.
2026-10-10 · System-boundary convention only; no claim that a selected boundary makes a system isolated.
Foundational review
2026-10-10 · Fresh primary-source inspection of the complete compact record, including every statement, equation, quantity and material condition, followed by independent AI editorial review. This check does not certify all linked lessons or every passage of every cited publication.
Sources from other places
Agreement within this scope
Choosing a system boundary determines which components, interactions and transfers count as internal or external.
A boundary is chosen for the problem; matter and energy exchanges then belong in the system description.
A free-body diagram represents all external forces acting on the selected body or system. Forces the system exerts on its surroundings belong on another system’s diagram. A force and its components are alternative representations, and the net force is their sum rather than an extra force. For an extended body, force locations are also needed to determine torque.
This relation concerns the stated free-body diagrams and system boundaries claim and its conditions; it does not assert an unqualified prerequisite or an additional theorem.
For a Newtonian particle under time-independent conservative forces plus other forces, E_mech=K+U and ΔE_mech=W_other. When the other forces do zero work, mechanical energy stays constant. Friction can convert ordered mechanical energy into internal energy; loss of K+U is compatible with total-energy conservation for a correctly chosen combined system.
This relation concerns the stated mechanical-energy conservation and dissipation claim and its conditions; it does not assert an unqualified prerequisite or an additional theorem.
For a mechanically quasistatic simple compressible closed system, work done by the system is W=∫p dV: expansion contributes positive work and compression negative work. A quasistatic isothermal ideal gas with fixed amount gives W=nRTln(V_f/V_i). Isochoric means constant volume; isobaric constant pressure; isothermal constant temperature; adiabatic means no heat transfer.
This relation concerns the stated pressure–volume work and process paths claim and its conditions; it does not assert an unqualified prerequisite or an additional theorem.
A reversible ideal process can be reversed so both system and surroundings return to their original states. A quasistatic model moves through a succession of nearly equilibrium states, allowing state variables along the path; slowness alone does not remove friction or finite-gradient entropy production. Free expansion of an insulated ideal gas can leave its temperature unchanged while remaining irreversible.
This relation concerns the stated reversible and quasistatic processes claim and its conditions; it does not assert an unqualified prerequisite or an additional theorem.
A measuring instrument is a device used to make measurements, alone or with supplementary devices. A measuring system is a set of one or more instruments and often other devices, reagents or supplies assembled to give quantity values within specified intervals for specified kinds of quantity. A single instrument can itself be a measuring system when it fulfils that role.
This relation concerns the stated measuring instrument and measuring system claim and its conditions; it does not assert an unqualified prerequisite or an additional theorem.
An open thermodynamic system permits matter to cross its boundary; a closed system permits no matter transfer but may exchange energy. An isolated system exchanges neither matter nor energy. Adiabatic means no heat transfer during the process: work can still transfer energy, so an adiabatic closed system need not be isolated.
A thermodynamic boundary is a particular application of the existing system-boundary definition.
Learning guidance · 5 / 5
Preserved learning suggestions. They are not proof, empirical evidence or mandatory prerequisites.