Localized orbital diamagnetic contribution
For a rotationally symmetric localized electronic orbital, the quadratic magnetic-field term in the nonrelativistic Hamiltonian gives δE=e²B²⟨r²⟩/(12m_e).
Key knowledge
For a rotationally symmetric localized electronic orbital, the quadratic magnetic-field term in the nonrelativistic Hamiltonian gives δE=e²B²⟨r²⟩/(12m_e). The corresponding negative orbital susceptibility contribution for number density n of those electronic contributions is χ_d=−μ₀ne²⟨r²⟩/(6m_e).
Values and equations
δE=e²B²⟨r²⟩/(12m_e); χ_d=−μ₀ne²⟨r²⟩/(6m_e)
- δE
- Energy shift per counted electronic contribution J
- e
- Positive elementary-charge magnitude C
- B
- Uniform induction T
- ⟨r²⟩
- Mean squared orbital radius m²
- m_e
- Electron mass kg
- n
- Number density of counted electronic contributions m⁻³
- μ₀
- Vacuum permeability N A⁻²
- χ_d
- Dimensionless orbital susceptibility contribution
Conditions and scope
- Weak uniform field, localized rotationally symmetric electronic probability, orbital radius measured about its localization center and a consistent count of contributing electrons.
- This isolates the A² orbital contribution. Other spin/orbital mixing terms, including Van Vleck response, can be important; a zero total angular momentum does not universally guarantee that the total material response is diamagnetic.
Sources · 1
References
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Evidence and review
Solid State Physics: third-year lecture notes (2012): §18.5: rotational average of the quadratic A² term, energy shift, induced moment and equation 18.13. Excludes the overly broad prose implication that this is the only magnetic response whenever J=0.
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