Separating electrode kinetics from transport
Research context
research method · established · As of 2026-10-10
Current–potential data can reflect charge transfer, bulk migration/diffusion, homogeneous reactions and evolving surface structure.
Key knowledge
Current–potential data can reflect charge transfer, bulk migration/diffusion, homogeneous reactions and evolving surface structure. Fit and test the coupled transport/reaction model under controlled boundaries before attributing a current slope or limiting regime to an elementary mechanism.
Conditions and scope
- State ionic strength/activity model, electrode geometry, pH, convection and potential convention; a concentration-limited current is not an equilibrium constant.
Sources · 3
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Electrochemistry 6.3: Nernst–Planck flux: Diffusion, migration and convection contributions (relevant full-text sections); Electrochemistry 6.4: Concentrated electrolyte transport: Stefan–Maxwell cross-species friction, concentration and electroneutral formulation (relevant full-text sections); Structure Sensitivity and Catalyst Restructuring for CO2 Electro-reduction on Copper: Main: DFT surface models, CO-induced reconstruction and STM comparison (relevant full-text results/discussion)
2026-10-10 · Bounded author source inspection of separating electrode kinetics from transport, including the stated conditions; independent branch review is recorded separately.
Entry details
Permanent link to this entry ↗- Record identity
- res-chem-electrode-inference
- Revision
- research.1
- Structured reference record
- Postgraduate & research reference