Dilute Nernst–Planck transport
Research context
postgraduate concept · conditional · As of 2026-10-10
A dilute-solution Nernst–Planck flux combines diffusion, electric migration and convection.
Key knowledge
A dilute-solution Nernst–Planck flux combines diffusion, electric migration and convection. Species balances, electrolyte current and reaction boundary fluxes must be solved together; bulk electroneutrality excludes resolution of the interfacial charge layer.
Values and equations
N_i = -D_i*grad(c_i) - z_i*D_i*F*c_i/(R*T)*grad(phi) + c_i*u
- N_i
- molar species flux mol m^-2 s^-1
- D_i
- diffusion coefficient m^2 s^-1
- c_i
- concentration mol m^-3
- z_i
- signed charge number 1
- F
- Faraday constant C mol^-1
- R
- gas constant J mol^-1 K^-1
- T
- temperature K
- phi
- potential V
- u
- solvent velocity m s^-1
Conditions and scope
- Assumes the dilute mobility–diffusivity relation, specified solvent velocity and constitutive coefficients; impose physical electrode/bulk boundaries.
Sources · 2
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Electrochemistry 6.3: Nernst–Planck flux: Diffusion, migration and convection contributions (relevant full-text sections); Electrochemistry 6.3: Tertiary current distribution, Nernst–Planck: Electroneutrality and electrolyte current closure (relevant full-text sections)
2026-10-10 · Bounded author source inspection of dilute nernst–planck transport, including the stated conditions; independent branch review is recorded separately.
Entry details
Permanent link to this entry ↗- Record identity
- res-chem-nernst-planck
- Revision
- research.1
- Structured reference record
- Postgraduate & research reference