Size-exclusion calibration and molar mass
Research context
research method · established · As of 2026-10-10
Size-exclusion results depend on column, solvent and calibration, so retention-based molar masses are not intrinsically absolute.
Key knowledge
Size-exclusion results depend on column, solvent and calibration, so retention-based molar masses are not intrinsically absolute. Independent light-scattering or other molar-mass measurements can reveal calibration-dependent differences, particularly for different polymer architectures.
Conditions and scope
- Report detector response, soluble sample fraction, calibration material and chromatographic conditions; aggregation or insoluble networks can evade measurement.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Size-exclusion chromatography of epoxy resins: IUPAC round-robin: Calibration, solvent/column dependence and independent molar-mass detectors (authored IUPAC report summary)
2026-10-10 · Bounded author source inspection of size-exclusion calibration and molar mass, including the stated conditions; independent branch review is recorded separately.
Entry details
Permanent link to this entry ↗- Record identity
- res-chem-sec-calibration
- Revision
- research.1
- Structured reference record
- Postgraduate & research reference