Ligand fields and spin-state competition
In an octahedral crystal-field model, d orbitals separate into a lower t2g set and an upper eg set.
Key knowledge
In an octahedral crystal-field model, d orbitals separate into a lower t2g set and an upper eg set. For eligible electron counts, the competition between splitting and electron-pairing energy produces different spin occupations. Geometry and ligand interactions affect splitting; crystal-field electrostatics is an approximation to metal–ligand electronic structure.
Conditions and scope
- The high/low-spin choice depends on d count, geometry and energetic competition.
- The model does not include all covalency, charge-transfer or many-electron effects.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Inspected octahedral splitting, high/low-spin cases and other geometry qualification.
2026-10-10 · Independent AI editorial review: All 94 actual compact claims, hypotheses, equation/variable/unit tables and 176 origin semantic links independently read. All exact author source-binding rows and disclosed extents assessed; targeted original bodies or specifically identified indexed primary passages rechecked below. All retained chemistry compact records read for combined breadth. Independent AI editorial content and practical common-core inventory review; no human specialist, degree/laboratory proficiency, whole-textbook certification or experimental replication. Receipt: chemistry-independent-content-inventory-review.1.
Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-crystal-ligand-fields
- Revision
- core.1
- Structured reference record
- University core expansion