Diels–Alder cycloaddition
In a typical thermal Diels–Alder reaction, a conjugated diene and a dienophile form two σ bonds and a new π bond through a concerted cyclic pathway.
Key knowledge
In a typical thermal Diels–Alder reaction, a conjugated diene and a dienophile form two σ bonds and a new π bond through a concerted cyclic pathway. The diene needs an accessible s-cis conformation; dienophile substituent geometry is retained in the corresponding product arrangement.
Conditions and scope
- Orbital overlap, substituents and geometry control reactivity and selectivity.
- Concerted thermal behaviour here is not a claim covering every cycloaddition or photochemical pathway.
Sources · 2
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Inspected cyclic bond changes, s-cis requirement and stereospecific relation.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-diels-alder
- Revision
- core.1
- Structured reference record
- University core expansion