Mass-to-charge and fragmentation evidence
A mass spectrometer ionizes material, separates ions by mass-to-charge ratio and detects their abundance.
Key knowledge
A mass spectrometer ionizes material, separates ions by mass-to-charge ratio and detects their abundance. Ionization and fragmentation produce method-dependent spectral patterns. A molecular ion, isotope pattern and fragments can constrain composition and connectivity, but the measured m/z is not automatically a neutral molecular mass.
Conditions and scope
- Specify charge state, ion type, ionization and analyser conditions.
- A molecular ion can be weak or absent; isomers and mixtures may need complementary evidence.
Sources · 1
References
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Evidence and review
Inspected source/analyser/detector, electron-ionization fragmentation and m/z separation; extended no specific uninspected ion-source technique.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-mass-spectrometry
- Revision
- core.1
- Structured reference record
- University core expansion