Spin coupling and NMR multiplets
Coupled nuclear spins can split resonances into multiplets.
Key knowledge
Coupled nuclear spins can split resonances into multiplets. In a simple first-order proton spectrum, coupling to n equivalent spin-½ neighbours gives an n+1 pattern with binomial intensities. Coupling constants and chemical shifts are distinct spectral quantities.
Conditions and scope
- The simple rule requires appropriate weak coupling and equivalent neighbours; overlapping couplings or strong-coupling effects can invalidate it.
- Equivalent protons do not ordinarily split each other in the simple interpretation; exchange can change observed patterns.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Inspected neighbour-spin mechanism and n+1 examples; kept first-order regime explicit.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-nmr-coupling
- Revision
- core.1
- Structured reference record
- University core expansion