Oxidative addition and reductive elimination
In a common mononuclear two-electron oxidative addition, a substrate bond is replaced by two metal–ligand bonds and the metal's formal oxidation state increases by two.
Key knowledge
In a common mononuclear two-electron oxidative addition, a substrate bond is replaced by two metal–ligand bonds and the metal's formal oxidation state increases by two. Reductive elimination reverses that accounting by forming a ligand–ligand bond. These transformations connect steps in catalytic cycles, with several possible detailed mechanisms.
Conditions and scope
- The stated counting applies to the common mononuclear pattern; binuclear and other mechanisms require separate accounting.
- Formal oxidative addition is a reaction class, not proof of one concerted elementary pathway.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Inspected formal count changes, mechanistic alternatives and binuclear qualification; did not adopt the source's conflicting universal electronic-requirement sentence.
2026-10-10 · Independent AI editorial review: All 94 actual compact claims, hypotheses, equation/variable/unit tables and 176 origin semantic links independently read. All exact author source-binding rows and disclosed extents assessed; targeted original bodies or specifically identified indexed primary passages rechecked below. All retained chemistry compact records read for combined breadth. Independent AI editorial content and practical common-core inventory review; no human specialist, degree/laboratory proficiency, whole-textbook certification or experimental replication. Receipt: chemistry-independent-content-inventory-review.1.
Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-oxidative-addition
- Revision
- core.1
- Structured reference record
- University core expansion