Functional-group step-growth polymerization
Step-growth polymerization joins compatible functional groups on monomers and oligomers rather than requiring all growth at one persistent chain centre.
Key knowledge
Step-growth polymerization joins compatible functional groups on monomers and oligomers rather than requiring all growth at one persistent chain centre. Difunctional acid/amine or ester/alcohol chemistry can form polyamides or polyesters. Diol/isocyanate addition gives a polyurethane linkage, showing that step growth need not release a small-molecule condensation product.
Conditions and scope
- Functionality, stoichiometric balance, conversion and side reactions affect chain length and branching.
- The statement distinguishes growth mechanisms; it does not claim every polyamide or polyurethane is made by one industrial route.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Read difunctional/oligomer linkage and diol-isocyanate addition; excluded incorrect implication that every Nylon6 preparation is classical step growth.
2026-10-10 · Independent AI editorial review: All 94 actual compact claims, hypotheses, equation/variable/unit tables and 176 origin semantic links independently read. All exact author source-binding rows and disclosed extents assessed; targeted original bodies or specifically identified indexed primary passages rechecked below. All retained chemistry compact records read for combined breadth. Independent AI editorial content and practical common-core inventory review; no human specialist, degree/laboratory proficiency, whole-textbook certification or experimental replication. Receipt: chemistry-independent-content-inventory-review.1.
Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-step-growth-polymerization
- Revision
- core.1
- Structured reference record
- University core expansion