Solid solution, tie lines and exsolution
A solid solution accommodates component substitution in one crystal phase.
Key knowledge
A solid solution accommodates component substitution in one crystal phase. Within a solid-plus-liquid or two-solid field, a tie line connects equilibrium phase compositions at the same temperature and pressure. A solvus bounds a two-solid coexistence region; cooling through it can produce exsolution if diffusion and nucleation allow the required compositional separation.
Conditions and scope
- Use the measured or thermodynamically justified diagram and consistent composition basis; coupled substitutions must preserve charge and lattice-site accounting.
- Equilibrium composition differs from a crystal's preserved core/rim zoning. Diffusion rates, cooling history and strain can retain a metastable homogeneous phase or incomplete exsolution.
Sources · 1
References
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Evidence and review
Read the actual solid-solution/tie-line and exsolution bodies including paired plagioclase substitution. No universal complete-solubility or geological cooling-rate inference adopted.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-earth-solid-solution-solvus
- Revision
- core.1
- Structured reference record
- University core expansion