Diffraction structure factor and systematic absences
For a cell basis, the kinematic elastic scattering amplitude contains F(G)=Σ_α f_α(G)exp(iG·d_α), and peak intensity is proportional to |F(G)|² with experiment-specific factors.
Key knowledge
For a cell basis, the kinematic elastic scattering amplitude contains F(G)=Σ_α f_α(G)exp(iG·d_α), and peak intensity is proportional to |F(G)|² with experiment-specific factors. Identical bcc atoms in the conventional cubic description cancel reflections with odd h+k+l.
Values and equations
F(G)=Σ_α f_α(G)e^[iG·d_α]; I(G)∝|F(G)|²; F_bcc=f[1+(−1)^(h+k+l)]
- F,f_α
- Structure/atomic scattering amplitudes; probe-dependent units
- G
- Reciprocal vector m⁻¹
- d_α
- Basis position m
- I
- Intensity with experiment-dependent normalization
- h,k,l
- Conventional cubic Miller indices
- i
- Imaginary unit
Conditions and scope
- Kinematic single-scattering approximation and consistently defined atomic scattering factors; phase-sign convention does not change intensities.
- Atomic form factors depend on probe and momentum transfer. Multiple scattering, thermal motion and finite-size effects require corrections.
Sources · 1
References
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Evidence and review
Solid State Physics: third-year lecture notes (2012): Section 13.2, equations 13.4–13.10 and §13.2.1 bcc cancellation example; applies the source's unit-cell Fourier sum to an atomic basis.
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