Mass and charge balances in solution
Quantitative aqueous speciation combines equilibrium relations with conservation of analytical amounts and electroneutrality.
Key knowledge
Quantitative aqueous speciation combines equilibrium relations with conservation of analytical amounts and electroneutrality. A monoprotic acid has an analytical balance cT=[HA]+[A⁻]; water and all dissolved ions must also satisfy a charge balance. These equations can be solved together rather than assuming one dissociation fraction for every concentration.
Conditions and scope
- Include all relevant dissolved species, complexes and counterions; a balance changes when material precipitates or another phase is present.
- Concentrations in balances count amounts; equilibrium constants require consistent activity corrections.
Sources · 1
References
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Evidence and review
Inspected mass-balance and charge-balance solution strategy in Harvey section 6.7; model excludes unlisted species.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-aqueous-mass-charge-balance
- Revision
- core.1
- Structured reference record
- University core expansion