Potentiometry and ion-selective response
Potentiometry measures the potential difference between an analyte-responsive indicator electrode and a reference electrode with negligible measurement current.
Key knowledge
Potentiometry measures the potential difference between an analyte-responsive indicator electrode and a reference electrode with negligible measurement current. Equilibrium response depends on activity. Ion-selective membranes and redox electrodes require their own response/selectivity models and calibration.
Conditions and scope
- Reference stability, junction potential, interfering ions and equilibration influence inference.
- A logarithmic activity response is not automatically a concentration reading.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Read electrode roles, activity-based potential relation, membrane-electrode and junction discussion; did not copy source's anode/cathode subscript error or a universal ideal response.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-potentiometric-evidence
- Revision
- core.1
- Structured reference record
- University core expansion