Representative analytical sampling
An analytical result concerns the sampled material; inference to a larger population requires a defensible sampling plan.
Key knowledge
An analytical result concerns the sampled material; inference to a larger population requires a defensible sampling plan. Sampling location, time, sample size and number, heterogeneity and preservation affect the result. Replicate instrument readings of one aliquot do not quantify between-sample variability.
Conditions and scope
- Define the target population and sampling design before interpreting a mean as representative.
- Selection bias and changes during storage cannot be removed merely by increasing instrumental precision.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Inspected population/design, homogeneous versus heterogeneous material and sampling-size discussion.
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Entry details
Permanent link to this entry ↗- Record identity
- uni-chem-sampling
- Revision
- core.1
- Structured reference record
- University core expansion