Peritectic reactions and incongruent melting
In a binary peritectic equilibrium at fixed pressure, an earlier solid and liquid react to form a different solid at an invariant temperature.
Key knowledge
In a binary peritectic equilibrium at fixed pressure, an earlier solid and liquid react to form a different solid at an invariant temperature. Heating that compound can produce a compositionally different solid plus liquid, which is incongruent melting. Removing the earlier solid during fractional crystallization can prevent the same reaction and change the final assemblage.
Conditions and scope
- Use the actual phase diagram and reaction stoichiometry; the invariant has two components and three coexisting phases at fixed pressure.
- Diffusion through a reaction rim may prevent equilibrium completion. A diagram alone does not establish that a natural rock followed its closed-system path.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Read the actual incongruent/peritectic definition, Fo+liquid→En reaction and equilibrium versus fractional examples. Preserved only the generic supported reaction/path distinction; excluded example temperatures and interpreting the liquid as pure silica.
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Entry details
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