Batch melting and fractional crystallization models
In homogeneous constant-D batch melting, mass balance and equilibrium give melt enrichment Cℓ/C₀=1/[D+F(1−D)].
Key knowledge
In homogeneous constant-D batch melting, mass balance and equilibrium give melt enrichment Cℓ/C₀=1/[D+F(1−D)]. For ideal fractional crystallization with immediate solid separation, residual liquid follows Cℓ/C₀=f^(D−1). These are different process models with different liquid-fraction conventions.
Values and equations
Batch: Cℓ/C₀=1/[D+F(1−D)]; fractional crystallization: Cℓ/C₀=f^(D−1)
- Cℓ,C₀
- liquid and initial bulk concentrations same concentration unit
- D
- constant solid/liquid distribution coefficient 1
- F
- mass fraction melted in batch model 1
- f
- mass fraction liquid remaining in fractional-crystallization model 1
Conditions and scope
- Batch F is fraction melted; crystallization f is liquid fraction remaining. Use 0<F≤1 and 0<f≤1 in the stated regimes.
- Constant D, homogeneous/modal behaviour and appropriate equilibration are assumptions; nonmodal melting, changing assemblages and mixing require extensions.
Sources · 1
References
Sources retain their recorded scope. A source link alone does not establish verification of every statement.
Evidence and review
Read batch-melting mass balance and fractional-crystallization formula plus multiphase/nonmodal limitations; did not validate all chapter values.
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Entry details
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- uni-earth-trace-element-models
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- core.1
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- University core expansion